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This difference in the electrostatic energy, called the exchange energy, appears as an interaction between the two electrons which depends on their relative orientation (although this dependence is incidental).

Exchange is the mechanism by which the electron spins in many magnetic materials are lined up parallel or opposed (for example, in α-iron and the ferrites).

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The distribution in space of the two electrons is different in these two states, and so their mutual electrostatic energy is different.

It is also the mechanism whereby the electron spins are parallel in the first excited state of the helium atom, and the spins of the two electrons are opposed in the carbon-carbon covalent bond.

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Exchange effects arise for all kinds of elementary particles, but these effects were first introduced into physics in consideration of atomic structure and the energy of the electrons in an atom.

In this context, they arise as a consequence of two facts: electrons are indistinguishable, and they obey the Pauli exclusion principle.